Article | REF: J5680 V2

Kerosene alkylation of olefins

Author: Jean-François JOLY

Publication date: September 10, 2009

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AUTHOR

  • Jean-François JOLY: Engineer from the École supérieure de chimie industrielle de Lyon - Doctoral engineer, University of Lyon - Head of the Reaction and Reactor Modeling Department at IFP

 INTRODUCTION

The process of alkylating olefins with kerosenes was developed in the 1930s, and enjoyed a boom at the start of the Second World War to produce high-octane aviation fuels. More recently, the growing demand for gasoline and the reformulation of fuels (in particular, lower sulfur and aromatic content) has led to an increase in alkylate production capacity worldwide. Alkylates offer significant advantages over gasolines produced by other processes: their high octane rating helps to compensate for the disappearance of lead from gasoline, their low toxicity and their combustion give rise to the least polluting emissions.

The alkylation reaction involves reacting an isobutane molecule with a light olefin molecule to produce a gasoline cut consisting of kerosenes with carbon numbers between 5 and 12.

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Kerosene alkylation of olefins