Article | REF: IN163 V1

A unique molecular design for excimer OLEDs based on oligophenylenes

Authors: Cyril PORIEL, Joëlle RAULT-BERTHELOT

Publication date: May 10, 2013

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Overview

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ABSTRACT

Dispirofluorene-indenofluorenes associate fluorenyl derivatives to the flat and rigid indenofluorenyl units. The architecture of these molecules is three-dimensional and their electronic properties are modulated by the nature and geometry of the various ? systems. Certain of these molecules with a geometry allowing intramolecular interactions between two ? systems positioned in a "face-to-face " configuration lead to a blue emission which would be impossible to achieve by the emission of independent ?-systems. The use of a blue light from intramolecular excimers in electroluminescent organic diodes is presented in this article.

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AUTHORS

  • Cyril PORIEL: Doctorate from the University of Rennes 1 - CR1 CNRS, Institute of Chemical Sciences of Rennes, UMR CNRS 6226, University of Rennes 1

  • Joëlle RAULT-BERTHELOT: Doctor of Science - DR2 CNRS, Institute of Chemical Sciences of Rennes, UMR CNRS 6226, University of Rennes 1

 INTRODUCTION

Key points

Field: Organic electronics, organic semiconductors

Degree of technology diffusion: Emergence | Growth | Maturity

Technologies involved : Organic light-emitting diodes

Applications: Display / Lighting

Main French players: Orgatech (LPICM, École Polytechnique), Elorga (Bordeaux), Plate-forme OLED 200 mm (CEA-LETI Grenoble), Plate-forme Organique IEMN (Villeneuve d'Ascq), Plate-forme Électronique Plastique (XLIM Limoges), Institut d'électronique du solide et des systèmes (InESS Strasbourg).

Competitive clusters: Minalogic, Tenerrdis

Competence centers: Organic Electronics Research Group (GDR 3368)

Manufacturers :

Other global players: Siemens + Osram, Philips, Sony + Panasonic, Mitsubishi Electric, Verbatim, Konica Minolta, LG Chem, Inteltronic, DuPont Display, General Electric, Holst center....

Contact: Cyril Poriel – Joëlle Rault-Berthelot, Groupe MaCSE, UMR CNRS 6226 Institut des Sciences Chimiques de Rennes, 35042, France [email protected] ; [email protected]

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A unique molecular design for oligophenylene-based excimer OLEDs