Overview
FrançaisABSTRACT
Cosmetic products have to be protected against oxidative degradation that causes unpleasant odors or color change. The presence of natural or synthetic antioxidants is essential to protect the products from the main causes of oxidation: oxygen, ultraviolet ray, heat, metal ions or photo-sensibilizers. Raw materials subject to oxidation are for the most part unsaturated fatty acids such as oils. As oxidative mechanisms are well known, several methods have been developed to evaluate the antioxidant potential of active molecules in cosmetics. Storage and packaging play a crucial part in optimizing protection.
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Read the articleAUTHORS
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Xavier FERNANDEZ: Doctor of Science, HDR - Professor at the University of Nice-Sophia Antipolis - Director, Master 2 Professionnel chimie formulation, analyse et qualité (FOQUAL) - Nice Institute of Chemistry UMR CNRS 7272, University of Nice-Sophia Antipolis
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Florence MERCK: Master's degree in plant resource development (University of Strasbourg) - Doctoral student in chemistry - Nice Institute of Chemistry UMR CNRS 7272, University of Nice-Sophia Antipolis
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Audrey KERDUDO: Chemical engineer (ENSC Rennes) - Doctoral student in chemistry - SOFIA Cosmetics - Nice Institute of Chemistry UMR CNRS 7272, University of Nice-Sophia Antipolis
INTRODUCTION
A major asset to the French economy, the cosmetics industry is a very active market, representing average sales of 16 billion euros a year.
With an average expenditure of 205.45 euros per year per inhabitant (in 2009) on hygiene, perfumery and beauty products, the French are the 4th biggest consumers of cosmetics in the world, behind the United States, Japan and Brazil.
Within this lucrative market, organic and natural cosmetics are steadily expanding, in response to growing consumer demand.
A cosmetic product is defined as "any substance or preparation intended to be placed in contact with the various superficial parts of the human body or with the teeth and oral mucous membranes with a view, exclusively or mainly, to cleaning them, perfuming them, modifying their appearance and/or correcting body odors and/or protecting them or maintaining them in good condition".
Whatever the nature of the cosmetic product, it must offer the consumer a certain organoleptic and sensory pleasure, but must also comply with safety conditions so as not to compromise the user's health.
To this end, it is essential to protect cosmetic products from the harmful effects of oxidation by adding antioxidant preservatives and controlling storage and packaging parameters. This ensures that the product lasts a sufficiently long time, and that consumers enjoy optimum use.
Antioxidants used in cosmetics can be of synthetic or natural origin. While the trend is to reject products of synthetic origin, and some results question the safety of synthetic antioxidants such as BHA or BHT, natural antioxidants are at the center of interest and widely studied.
The criteria for choosing one or more antioxidants are complex, since good antioxidant efficiency means protection against oxidation caused by air, but also against photo-induced oxidation, as well as against catalytic factors such as temperature and the presence of metallic traces or certain photosensitizing elements. In addition, the antioxidant agent must not alter the product's odor, appearance or color, nor be toxic or allergenic.
So, in order to propose a formula with optimized antioxidant protection, it is important to understand which factors induce oxidation, which raw materials and which cosmetic products are particularly affected by oxidative degradation, and what the resulting degradation mechanisms are. Understanding these elements then enables us to better define the role that the antioxidant agent should play in the formula, and to choose the most appropriate one, whether synthetic or natural. Other parameters, such as packaging or the addition of raw materials that potentiate the antioxidant...
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KEYWORDS
antioxidants | préservatives | anti UV | |
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Preservatives for cosmetics
Bibliography
Websites
CIR: Cosmetic Ingredient Review http://www.cir-safety.org/ (page consulted February 14, 2012)
COSMOS-standard AISBL: European COSMOS standard for organic cosmetics http://www.cosmos-standard.org/ (page consulted February...
Events – Congresses
Beyond Beauty Events – International trade fairs for beauty and wellness suppliers and brands http://www.beyondbeautyevents.com/bbe/fr/bbe_00_Home.asp
Beauty & Packaging Conference – Perfume and cosmetics packaging
Standards and norms
- Animal and vegetable fats – Determination of acid number and acidity - NF EN ISO 660 -
- Animal and vegetable fats – Determination of ultraviolet absorbance, expressed as specific extinction in ultraviolet light - NF EN ISO 3656 -
- Animal and vegetable fats – Determination of iodine index - NF EN ISO 3961 -
- Animal and vegetable fats – Determination of peroxide value – Determination with iodometric...
Regulations
Commission Decision 96/335/EC of 8 May 1996 establishing an inventory and a common nomenclature of ingredients employed in cosmetic products (text with EEA relevance). Official Journal L 132 of 01/06/1996 p. 0001-0684
Council Directive 76/768/EEC of July 27, 1976 on the approximation of the laws of the Member States relating to cosmetic products
Directory
Manufacturers – Suppliers – Distributors (non-exhaustive list)
Preservative suppliers
ARCH CHEMICALS (LONZA) http://www.archchemicals.com/fed/pc (page consulted on March 20, 2012)
CLARIANT http://www.personalcare.clariant...
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