Overview
ABSTRACT
As it does not exist naturally on earth, hydrogen is mainly produced from fossil fuels and a little by electrolysis. Today, it is widely used in the chemical industry and refining and will be even more so in the future. After a presentation of the hydrogen market and its evolution, this article describes the entire chain of hydrogen from its production up to its storage and transportation. Due to its clean burning, non-polluting combustion, it is also considered to be one of the energy carriers of the future. If the use of hydrogen is mastered industrially, the security issues, particularly for this possible future should be taken into account.
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Karine SURLA: Engineer École nationale supérieure des mines de Saint Étienne - Doctorate in process engineering from INPG and Mines de Saint Étienne - Head of hydrogen projects at IFP Énergies nouvelles IFP Énergies Nouvelles-Lyon Rond-point de l'échangeur de Solaize, Solaize, France
INTRODUCTION
Hydrogen is the most widespread element in the universe: it is the main constituent of the sun, giant planets like Jupiter and Saturn, most stars and interstellar and intergalactic matter.
On earth, hydrogen is most often combined with other elements to form molecules such as water, hydrocarbons or even more complex molecules such as proteins or carbohydrates. Also, the H 2 or dihydrogen molecule, although observed, in emissions from certain ridges, exists very little in its natural state. To be used, therefore, the element hydrogen must first be separated from its host molecule to be recombined into dihydrogen molecules, which is generally a very energy-intensive operation. In short, it has to be produced. To date, hydrocarbons are the main source of industrial hydrogen, via mature production processes such as steam reforming, with the disadvantage of co-producing carbon dioxide. Hydrogen plays an important role in the chemical industry, in oil refining and petrochemicals, and to a lesser extent in the production of certain materials. Today, however, its use as an energy carrier is very limited. However, because of its non-polluting combustion, it is also seen as a potential energy carrier of the future, provided that its production itself is non-polluting. The industry's expectations therefore focus first and foremost on clean, economically viable production. Hydrogen storage and distribution are two key points in the use of hydrogen as an energy carrier.
The aim of this article is to describe the entire hydrogen chain. It begins with an overview of the market, then describes existing technologies for hydrogen production and purification, as well as those under development. As the production of hydrogen from hydrocarbons is accompanied by carbon dioxide emissions, CO 2 capture and storage solutions are discussed. Hydrogen storage, transport and distribution methods are then discussed, as these are the three essential links in the chain between production and use. Finally, this article gives some background on the safety issues associated with the use of this molecule and the standards in force.
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KEYWORDS
energy | hydrocarbons | electrolysis
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Hydrogen
Bibliography
Events
WHEC (World Hydrogen Energy Conference). Under the aegis of the International Association for Hydrogen Energy IAHE, one of the world's largest and longest-running hydrogen energy conferences, the WHEC, has been held every two years since 1976. These conferences are organized in turn by the hydrogen-energy community of one country in the world
WHTC Congress. Annual World Conference on Hydrogen Technologies...
Standards
- Liquid Hydrogen – Land vehicle fuelling system interface - ISO 13984 - 1999
- Liquid hydrogen – Land vehicle fuel tank - ISO 13985 - 2006
- - ISO 14687:1999 -
- Hydrogen fuel – Product specification - ISO 14687:1999/Cor1 - 2001
- Airport H2 fuelling facility - ISO/PAS 15594 - 2004
- Basic considerations for the safety of hydrogen systems - ISO/TR 15916 - 2004
- Hydrogen generators using...
Patents
Cerium electrolytic oxidation process and electrolysis unit for its implementation CA2582058.
Process for the production of synthesis gas by steam reforming in a reactor-exchanger FR2890955, ROJEY (A.), BERTHOLIN (S.), GIROUDIERE (F.), LENGLET (E.).
Process for the production of highly thermally integrated hydrogen by reforming a hydrocarbon feedstock, EP 2107043, GIROUDIERE (F.),...
Directory
Manufacturers – Suppliers – Distributors (non-exhaustive list)
High-capacity hydrogen production (> 10,000 Nm 3 /h)
HALDOR TOPSOE AS http://www.topsoe.com
TECHNIP http://www.technip.com
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