Article | REF: BE8042 V2

Thermodynamic charts - Mixtures used in thermal machines

Author: Renaud GICQUEL

Publication date: October 10, 2015, Review date: September 10, 2021

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ABSTRACT

The behavior of mixtures differs profoundly from that of pure substances, because pressure and temperature do not remain constant during changes of state. In this paper, we explain this phenomenon in the first part, and go on to provide examples of mixture charts where three types of cycle are represented. The third part deals with mixtures used in absorption cycles.

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AUTHOR

  • Renaud GICQUEL: Professor - PSL – Research University, PERSEE – Centre procédés, énergies renouvelables et systèmes énergétiques, Mines ParisTech, Sophia Antipolis, France

 INTRODUCTION

This article [BE 8 042] and the following one Thermodynamic diagrams – Wet mixtures and combustion [BE 8 043] follow on from the articles Thermodynamic diagrams – General [BE 8 040] and Thermodynamic diagrams – Pure fluids, azeotropes and ideal gases [BE 8 041] in which diagrams relating to pure bodies and azeotropic mixtures were presented. They deal with the diagrams used to represent the properties of the thermodynamic fluid mixtures most commonly used in the various fields of power engineering, with the exception of cryogenics, which is not covered here (see article [B 2 380] ). In all these articles, except for the one on combustion [BE 8 043] , the mixtures considered are non-reactive.

This article is divided into two parts corresponding to distinct fields of application:

  • the study of temperature-slip refrigerant diagrams, an extension, for vapour mixtures of fixed composition, of the diagrams presented in paragraph 1 of article [BE 8 041]...

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KEYWORDS

charts   |   thermodynamic fluids   |   refrigeration   |   Organic Rankine Cycles   |   energy conversion   |   thermal machines


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Thermodynamic diagrams – Mixtures used in thermal machines