Article | REF: BE8041 V2

Thermodynamic charts - pure substances, azeotropes and ideal gases

Author: Renaud GICQUEL

Publication date: October 10, 2015, Review date: September 10, 2021

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ABSTRACT

The thermodynamic properties of pure substances can be graphically represented in a plane, in the form of thermodynamic charts. Several coordinate systems can be chosen depending on the use made of these diagrams. In this paper, we provide a dozen examples of charts and show how three types of cycle can be plotted in them.

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AUTHOR

  • Renaud GICQUEL: Professor - PSL – Research University, PERSEE – Centre procédés, énergies renouvelables et systèmes énergétiques, Mines ParisTech, Sophia Antipolis, France

 INTRODUCTION

This article follows on from the article Thermodynamic diagrams – Generalities [BE 8 040] in which the basic thermodynamics used to draw up the diagrams were presented. We refer the reader to this article for explanations of the equations used and for nomenclature.

The article itself is structured in three parts: first, the main types of diagrams used in practice are presented; a dozen examples relating to some common fluids are then given; finally, the representation in these diagrams of three basic thermodynamic cycles is explained (steam power plant cycle, R 134a refrigeration cycle, and gas turbine cycle).

Abbreviations

CFC

Chlorofluorocarbon

COP

Coefficient of performance

GWP...

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