Article | REF: IN404 V1

Artificial Diels-Alderases at the service of green chemistry

Authors: Wadih Ghattas, Jean-Pierre Mahy, Rémy Ricoux, A. Jalila Simaan, Marius Réglier

Publication date: September 10, 2021

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5. Metallo-Diels-artificial alderases

To our knowledge, no natural metallo-DAases have yet been identified. Indeed, while magnesium(II)-containing macrophomate synthase was initially thought to be a metallo-DAase, it was later shown to catalyze a sequential Michael-aldol addition . Nevertheless, early hypotheses proposing that the enzyme's operating mechanism involves the bidentate...

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