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Ernest MARÉCHAL: Associate Professor of Physics - Doctor of Science - Professor Emeritus at Pierre-et-Marie-Curie University (Paris)
INTRODUCTION
The aim of this article is to present the theoretical bases of polyaddition and polycondensation, in particular the definition of their main stages, their thermodynamics and kinetics; the contribution of secondary reactions is analyzed. Relationships allowing the control and distribution of molar masses, as well as those relating to the phenomenon of gelation, are given. The main polyaddition and polycondensation techniques are described, in particular those developed more recently.
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Polycondensation and polyaddition
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RheoPower (Software for detecting molecular weight distribution as a function of viscosity measurements. Modeling and simulation of distributions). TOMCOAT http://www.tomcoat.com
PolyEFF (Polymerization reaction simulator). EFFTech Engineering Software http://efftech.tripod.com
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