Overview
ABSTRACT
Rubber applications outside tires cover a wide range of uses in everyday life (seals, hoses, automotive, medical) and in high performance parts (aerospace, offshore). These applications make use of the specific characteristics of these polymers, a manufactured rubber item being obtained after compounding, mixing, forming and vulcanization stages. This article presents the applications of rubbers in terms of performance requirements with examples of formulations. The most popular applications are first stated (vibration dampeners and seals), followed by miscellaneous uses (gloves, cables and foams).
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Read the articleAUTHOR
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Yves de ZÉLICOURT: Doctorate in Chemistry from the Swiss Federal Institute of Technology, Zürich, Switzerland - Former consulting engineer at LRCCP (Laboratoire de recherches et de contrôle du caoutchouc et des plastiques)
INTRODUCTION
Non-tire rubber applications correspond to the so-called industrial rubber sector, which, in terms of manufacturing, involves a number of employees of the same order of magnitude as that of the tire sector (52 and 48% respectively out of a total of 58,000 employees in France in 2011 (doc. SNCP). On the other hand, unlike the tire industry, the industrial rubber business is spread across a large number of companies, both small and large.
In descending order of importance, industrial rubber covers: automotive (50%), non-automotive transport (14%), industrial equipment (12%), medical (7%), construction (7%), semi-finished products (5%), adhesive tapes (4%), sports and leisure (1%) (doc. SNCP).
In the automotive industry, for example, it faces competition from thermoplastic elastomers (TPEs), which are simpler to process, since the pellets marketed by producers are fed directly into injection molding machines or extruders. As in the case of rubbers, there is no mixing and vulcanization stage, not to mention the necessary prior formulation development required to achieve the performance levels demanded by the intended application and spelled out in the specifications. However, the advantage of rubbers over TPEs lies in their unrivalled properties, such as high elasticity, low compression and tensile set, fatigue resistance, tear strength...
What's more, certain special rubbers (silicones, fluorocarbons) can withstand high temperatures and chemicals, making them indispensable in high-performance applications such as aeronautics, offshore, turbo hoses, etc. Their limitation is their cost (orders of magnitude in [Doc. AM 8 605]), which far exceeds that of mass-market rubbers (natural rubber, SBR, EPDM).
Rubber manufacturers prepare their own "mixes" using specific tools (internal mixers and cylinder mixers). They therefore have their own formulas and their own mixing parameters, developed and constituting their know-how. The basic elastomer is gum, which is marketed by major groups in the case of synthetic rubbers – Lanxess, Zeon, Du Pont, Exxon... natural rubber is produced in descending order by Thailand (31%), Indonesia (27%), Malaysia (9%), India (8%), Vietnam (7%) and China (6%) – the remainder being produced in Africa and Brazil (doc. SNCP). In addition to gum, rubber formulas contain :
fillers (usually carbon black or silica);
vulcanizing agents;
oils ;
various processing and protective additives.
The second point that characterizes the rubber industry is the need to vulcanize it to give it better properties for use, which calls for...
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KEYWORDS
cables | seals | | gloves | belts | foams | vibrations filtrations
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Non-tire rubber applications
Bibliography
Software tools
Mooc (Massive Open Online Courses) discovering rubber: a remarkable material https://www.fun-mooc.fr
Websites
James Walker (high-performance seals) https://www.jameswalker.biz
Interep (foam rubber) http://www.interep.fr
LANXESS, Styrene Butadiene Rubber Solution (base elastomers) https://techcenter.lanxess.com
...Events
International Rubber Conference Organisation: annual international conference on the latest developments, products and research in the rubber industry. Each year, the conference is held in a different country. http://www.internationalrubberconference.org/
The world's largest trade fair for the plastics and rubber...
Standards and norms
- Rubber and latex – Parts list - NF ISO 1629 -
- Unvulcanized rubber – Determinations using a shear disk consistometer – Part 1: Determination of the Mooney consistometric index - NF ISO 289-1 -
- Unvulcanized rubber – Determinations using a shear disk consistometer – Part 2: Determination of prevulcanization characteristics - NF ISO 289-2 -
- Rubber – Determination of vulcanization characteristics...
Regulations
EC Regulation No. 1907/2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH).
Patents
There are countless patents in the rubber sector, given the huge variety of formulations developed by manufacturers for very specific functions. These form part of the know-how considered confidential by manufacturers.
Directory
Manufacturers – Suppliers – Distributors (non-exhaustive list)
A list of rubber manufacturers (raw materials suppliers, compound manufacturers, parts manufacturers, equipment suppliers) is published by CFCP (Centre français du caoutchouc et des polymères). http://www.lecaoutchouc.com
Organizations – Federations – Associations (non-exhaustive...
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