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Article | REF: AF6505 V1

Organometallic chemistry - Insertion reaction

Author: Yves JEANNIN

Publication date: October 10, 2000, Review date: March 30, 2015

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1. Insertion reactions with an 18-electron complex

It has been seen (cf. article [AF 6 501], § 1.2 , of this treatise) that the action of sodium on manganese carbonyl makes it possible to prepare the sodium derivative Na[Mn(CO) 5 ]. This compound reacts with ease with methyl iodide ICH 3 :

It's easy to see that manganese is always surrounded by 18 electrons:...

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Insertion reactions with an 18-electron complex
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