Article | REF: AF6505 V1

Organometallic chemistry - Insertion reaction

Author: Yves JEANNIN

Publication date: October 10, 2000, Review date: March 30, 2015

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2. Possibility of new syntheses

With this in mind, can we take advantage of this insertion to imagine reactions leading to new syntheses?

First of all, the nature of the pusher can be changed. If, for example, butadiene is used :

The carbon-carbon interaction can continue between the acetyl group and the butadiene end, and after migration of a hydrogen atom :

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Possibility of new syntheses