Article | REF: AF6505 V1

Organometallic chemistry - Insertion reaction

Author: Yves JEANNIN

Publication date: October 10, 2000, Review date: March 30, 2015

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5. Insertion reactions in the metal-hydride bond

The insertion reaction can also occur in a metal-hydride bond. Numerous variations exist, highlighting the richness of this insertion reaction. The simplest type of insertion involves an alkene being converted into an alkyl group. Differences in metal-hydrogen and metal-carbon electronegativity lead to a polarity that places the positive charge on the metal in both cases. The degree of oxidation of the metal does not change in this insertion:

Insertion reaction of ethylene and carbon dioxide into a metal-ligand bond via π-electrons
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Insertion reactions in the metal-hydride bond