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Article | REF: P3365 V2

Capillary electrophoresis Principles

Author: Nathalie DELAUNAY

Publication date: December 10, 2019, Review date: September 2, 2020

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2. Fundamental quantities

2.1 Migration time

In capillary electrophoresis, during an analysis, the detector signal is recorded as a function of time to obtain an electrophoregram, like the one shown in figure 5 . This makes it possible to determine the exit time at the peak, noted t m for migration time, of each analyte. This is equal to the ratio of the distance covered, which is the effective length

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