Article | REF: M2372 V1

Germanium-Metallurgy

Authors: Pierre BLAZY, El-Aïd JDID

Publication date: September 10, 2010

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1. Physical and chemical properties

Box 1 summarizes the main stages in germanium production.

Box 1 – Brief history

1886 – Germanium is isolated from argyrodite by Clemens Winkler.

1940-1945 – Use of germanium in radar installations (Sn-Ge diodes).

1946 – First processes for recovering germanium from zinc metallurgy.

1948 – Use of germanium in diodes (electronics, television, computers, telephony, special optical lenses, etc.).

1956 – New germanium purification techniques, production of single crystals, huge need for semiconductors.

1965 – Use of germanium oxide as a catalyst in the polymerization of Polyethylene Terephthalate (PET) in Japan.

1970 – Silicon replaces germanium in microelectronics.

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