Article | REF: N4004 V1

Luminescent hetero lanthanide coordination polymers - Characteristics and applications

Authors: Olivier GUILLOU, Carole DAIGUEBONNE, Chloé BLAIS

Publication date: September 10, 2024

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1. Coordination chemistry

The origins of coordination chemistry lie in the work of A. Werner at the end of the 19th century . Based on his work, Werner postulated that metal ions possess two types of valence: primary valence (today called oxidation number) and secondary valence (today called coordination number), which can be different.

A coordination compound can be defined as a polyatomic structure in which an ion of a transition element, i.e. an element from blocks d or f of the periodic table (figure

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Coordination chemistry