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ABSTRACT
The development of chemical reactions with limited environmental impact has become a priority for chemists. Catalysis and atom economy are essential in order to achieve green chemistry. The redox isomerization reaction which allows for the conversion of allylic alcohols to saturated carbonyl compounds is catalyzed by an organometallic complex; it is 100% atom-efficient as substrate and product are isomers (same gross chemical formula). A judicious choice of catalyst allows for the development of efficient synthetic methods which are alternatives to the sequential redox process traditionally used.
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Read the articleAUTHORS
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Vincent Bizet: Doctorate from the University of Rouen UMR 6014 COBRA, University and INSA of Rouen, Mont Saint Aignan
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Dominique Cahard: CNRS Research Director, UMR 6014 COBRA, Rouen University and INSA, Mont Saint Aignan
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Sylvain Gaillard: Associate Professor, University of Caen Basse Normandie, UMR 6507 Molecular and Thioorganic Chemistry Laboratory (LCMT)
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Jean-Luc Renaud: Professor, University of Caen Basse Normandie, UMR 6507 Molecular and Thioorganic Chemistry Laboratory (LCMT)
INTRODUCTION
Field: green chemistry
Degree of technology diffusion: Emergence / Growth / Maturity
Technologies involved: homogeneous catalysis
Applications: chemistry, biotechnology, materials
Key French players: Dr. R. Grée (Université de Rennes 1)
Other international players: Prof. J. Gimeno, Prof. C. Mazet, Prof. B. Martín-Matute.
Contact: [email protected]
http://jlrenaud6507.wix.com/renaudresearchgroup
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Unit operations. Chemical reaction engineering
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Redox isomerization: an atom-saving reaction with high innovation potential
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Professor Clément MAZET's group: http://www.unige.ch/sciences/chiorg/mazet/home_fr
Professor Belen MARTÍN-MATUTE's group : http://www.organ.su.se/bm/
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