Overview
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ABSTRACT
Photocatalysis is one of the advanced oxidation processes. The principle consists in generating radicals in-situ to degrade organic pollution. In the case of photocatalysis, OH* and O2*- radicals are generated by UV radiation on a semiconductor, often TiO2. This article is subdivided into 4 parts. A first part presents the fundamentals of photocatalysis. The second part deals with the development of the photocatalytic material (material supported and depositing TiO2) as well as the improvements made (material based on optical fibers). The third part deals with the implementation of photocatalysis in batch and continuous reactors. The influence of the operating parameters is also presented. Finally, in the last part, applications in indoor air treatment and industrial effluents are presented. The aspect of combining processes with photocatalysis for performance improvement is also discussed.
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Read the articleAUTHORS
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Aymen Amin ASSADI: Maître de conférences HDR Université Rennes, École nationale supérieure de chimie de Rennes, France
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Abdelkrim BOUZAZA: Senior Lecturer, University of Rennes, École Nationale Supérieure de Chimie de Rennes, France
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Dominique WOLBERT: Professor University of Rennes, École nationale supérieure de chimie de Rennes, France
INTRODUCTION
The emission of volatile organic compounds (VOCs) into ambient air has become a major public health issue in recent years. Numerous studies have shown that VOCs can be toxic, even carcinogenic, mutagenic or teratogenic. In addition to their direct effects on health, many compounds have very low odor thresholds and cause a major nuisance, both for site employees and neighbors. Their impact on the natural environment and on human health is therefore considerable . What's more, the growth of the human population and the creation of large cities have created new, more sedentary urban lifestyles, forcing people to expose themselves to a new type of atmospheric pollution: that linked to indoor air. Indeed, depending on climatic conditions, outdoor air is dispersed and washed by rain on a daily basis, whereas this is not the case for indoor air. This explains why most scientific research shows that the number and concentration of pollutants are much higher in indoor air than in outdoor air.
The problem of eliminating olfactory nuisance is a complex one, since the principle often lies in the treatment of a high-flow, low-load effluent, made up of a complex mixture of compounds, each of which contributes to the odorous "hue" .
The main families involved are sulfur derivatives (hydrogen sulfide, mercaptans, sulfides), nitrogen derivatives (ammonia, amines) and oxygen derivatives (volatile fatty acids, alcohols, aldehydes, esters). This diversity implies the use, preferably, of less selective depollution techniques, such as photocatalysis. Among the various processes that can be envisaged, it offers the advantage of requiring no reagents and generating as residue only the by-products of pollutant degradation, degradation that can be taken as far as mineralization (formation of CO
2
and H
2
O)
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KEYWORDS
reactor | air | photocatalysis | Langmuir-Hinshelwood | Depollution
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Unit operations. Chemical reaction engineering
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Photocatalysis for air treatment
Bibliography
Bibliography
Standards and norms
- Self-contained air cleaners for commercial and residential applications – Test methods – Intrinsic performance, AFNOR - NF B44-200 - 2016
- Photocatalysis – Measuring the effectiveness of photocatalytic devices for active-mode removal of VOCs and odors from indoor air – Part 1: Confined enclosure test method, AFNOR - NF EN 16846-1 - 2017
Directory
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Industrial equipment
France dehumidification Photo-Lux process: http://deshumidifications.com/index.php/photocatalyse/
UVRER-ANEMO: https://www.uvrer-anemo.com/traitement-de-lair-par-photocatalyse
CondorChem: https://condorchem.com/en/blog/photocatalysis-for-vocs-treatment/...
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