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1. Preparation of polyfunctionalized organometallic species
An organometallic compound has a more or less polarized carbon-metal bond. The more ionic the carbon-metal bond, the more reactive it is to electrophiles (E + ). On the other hand, the more covalent the carbon-metal bond, the more inert it will be to electrophiles, and consequently the more functional groups are tolerated in these organometallic species.
In practice, C-Mg and especially C-Zn bonds are compatible with a large number of functional groups, and efficient and general synthesis methods have been developed since the late 80s.
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Preparation of polyfunctionalized organometallic species
Continuous flow organometallic reactions
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