Overview
ABSTRACT
The development of batteries has been booming in recent years, particularly due to the increase in mobility applications (electronic and automotive devices). The two main technologies in volume today are lead and lithium-ion. In many cases, however, other electrochemical couples remain of particular interest whether for reasons of temperature or safety. This article will focus on Nickel-Metal-Hydride batteries from battery design to battery management. Application examples will also support the benefits of Ni-MH technology.
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Stéphane BLANCHIN: Accumulator/electrochemistry R&D design manager - ARTS Energy, Nersac, France
INTRODUCTION
The world's need for energy storage is growing rapidly. Electrochemical storage is one of the key components. The market for rechargeable batteries has almost doubled in 15 years, notably with the multiplication of nomadic applications, such as cell phones, laptops, tablets... At present, growth is being driven more by the development of electric, hybrid and rechargeable hybrid vehicles. Demand in this sector is creating strong pressure on production volumes for lithium-ion batteries, which are the key technology for the automotive sector thanks to their greater energy density than other rechargeable technologies. Lithium-ion technologies enable much higher mass and volume energy densities than other types (in excess of 200 Wh · kg –1 and 500 Wh · L –1 ). However, despite all the excitement surrounding lithium-ion technology, it has to be said that the "old" technologies still play an important role.
To illustrate this, it is interesting to analyze the different types of use. Electrochemical storage applications can be divided into several categories : starter battery, traction battery, on-board battery, stationary battery and portable battery. For each type of application, one or more technologies are used, depending above all on the characteristics required for the application: voltage (V), capacity (Ah), energy density (Wh · kg –1 or Wh · L –1 ), power requirement (W · kg –1 ), service life (number of cycles or duration of use for standby applications), temperature conditions (– 40 to + 80°C) and, of course, cost in €/kWh. Cost is an important component, but safety must never be overlooked. From this point of view, lithium technologies are by far the most sensitive, and require great care in system design.
In this context, the main technologies (figure 1 ) are :
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KEYWORDS
electrochimical storage | rechargeable batteries | Ni-MH accumulator
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Nickel-metal-hydride (Ni-MH) batteries
Bibliography
Websites
Panasonic catalog – Eneloop element https://www.panasonic-eneloop.eu
VARTA microbattery http://products.varta-microbattery.com
...Events
Congrès Batteries 2018, takes place every year in Nice
Show: Batimat Reed Expositions International construction show, held every two years in Paris (odd-numbered years). http://www.batimat.com
Captronic Day https://www.captronic.fr
...Standards and norms
- Alkaline and other non-acid batteries – Sealed batteries for portable applications – Part 2: Nickel-metal hydride - IEC 61951-2 - 2017
Patents
BECCU (K.). – Electrical Accumulator with a Metal Hydride Serving as the Cathodic Reactive Material Arranged in Suspension in the Electrolyte. U.S. Patent 3,520,728, July 14, 1970.
YASUYUKI (H.), TADAYOSHI (T.), YOSHIFUM (M.), KATSUHIKO (S.), TOSHIYUKI (N.) and IKUO (Y.). – Separator for nickel-metal hydride storage battery and nickel-metal hydride storage battery. Japanese Patent 2003068270 (A) – July...
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