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Article | REF: CHV2224 V1

Multicomponent reactions and radical chemistry

Authors: Yannick LANDAIS, Guy ROUQUET, Laurent HUET

Publication date: May 10, 2011

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2. Multi-component radical reactions

2.1 3-component radical reactions – Radical additions to olefins

Olefins provide a source of radical acceptors that can be used in a single transformation to produce highly sophisticated synthetic intermediates. This chapter describes a number of radical additions to olefins, leading to the formation of new C-C and C-N bonds under mild and, for the most part, non-polluting conditions.

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2.1.1 Carboazidation and carbodiazenylation reactions

  • The carboazidation of olefins...

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