Article | REF: CHV2224 V1

Multicomponent reactions and radical chemistry

Authors: Yannick LANDAIS, Guy ROUQUET, Laurent HUET

Publication date: May 10, 2011

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3. Ionic radical multicomponent reactions

3.1 Anionic radical multicomponent reactions

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3.1.1 Tandem anionic radical processes – Metals with little or no renewable potential

During a radical reaction between two components, the new radical species generated can then be reduced, leading to a new nucleophilic entity (carbanion, enolate...) which can be used in ionic processes. Given the relatively inert nature of radicals under ionic conditions and vice versa, it's not surprising that multicomponent reactions incorporating both radical and ionic processes...

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Ionic radical multicomponent reactions