Overview
ABSTRACT
Polycarbonate is a transparent material with very good resistance to shock and a heat-resistance of up to 120°. This amorphous thermoplastic material, discovered in 1953 and commercialized from 1958, has at this time a global consumption of 1,200,000 tons. It is mainly derived from the polycondensation of bisphenol A and a carbonate or the phosgene (carbonyl chloride). Although this fabrication process is currently the most widely used by main producers, regulation and applications are driving this technology towards a purer resin with lesser residual phosgene via the molten process.
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Jean-Marie DUMONT: Research and development engineer in plastics formulation
INTRODUCTION
Polycarbonate is an amorphous thermoplastic material discovered in 1953 by Schnell, Bottenbruch and Krimm, three researchers working for Bayer AG, and General Electric's D r Daniel W. Fox. First marketed in 1958, it currently consumes 1,200,000 tonnes a year worldwide.
Polycarbonate is a polymer derived from the polycondensation of bisphenol A and a carbonate or phosgene (carbonyl chloride). This manufacturing process is the most common and is still the most widely used by the main producers, but regulations and applications are directing the technology towards a purer, cleaner resin in terms of residual phosgene via the melt process.
The polycarbonate resins produced are either used directly or granulated with the appropriate additives, depending on the properties required for a specific application. The use of these additives in formulation is increasingly regulated in terms of health and safety.
The advantages of polycarbonate are that it's a transparent material with very good impact resistance, heat resistance allowing use up to 120 ˚C and excellent aesthetics thanks to its transparency. However, its sensitivity to chemical agents and ultraviolet light limits its use.
Recent years have seen the emergence of new and growing applications, particularly in the communications field, such as compact discs and versatile digital discs.
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Polycarbonates
References
Websites
Polymer science learning center http://www.pslc.ws/french/pc.htm
Comptec (bimaterial molding) http://www.comptec.fr
Design http://www.placeaudesign.com
...Standardization
International Organization for Standardization (ISO) http://www.iso.org
- Plastics – Determination of the melt flow rate of thermoplastics, by mass (MFR) and by volume (MVR). - ISO 1133 - (2005)
- Plastics – Determining tensile properties – Parts 1 to 4. - ISO 527 - (1993-1997)
- Plastics – Determination of bending properties. - ISO 178 - (2001)
- Plastics – Hardness determination – Part 1: Ball penetration...
Some regulatory texts
Council Directive 2001/102/EC of November 27, 2001 amending Directive 1999/29/EC on undesirable substances and products in animal nutrition (OJ L 6, 10.1.2002, p. 45-49).
Directive 96/82/EC, known as "Seveso II", amended by Directive 2003/105/EC of the European Parliament and of the Council of December 16, 2003 amending Council Directive 96/82/EC (OJ L 10, 14.1.1997 and OJ L 345, 31.12.2003)....
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