Article | REF: P1097 V2

Polymorphism; Basic principles and characterization methods

Author: Michel BAUER

Publication date: November 10, 2022 | Lire en français

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    A brief historical overview

    In 1788, Klaproth observed that calcium carbonate crystallized in two different forms: aragonite and calcite. In 1809, Humphrey Davy suggested that diamond and graphite corresponded to two different arrangements of carbon in the solid phase. In 1821, Mitscherlich published his observations on the existence of different crystalline forms for sodium monophosphate in French, introducing the term "polymorphism" . Shortly afterwards, he identified two allotropic forms of sulfur. From then on, the discovery of crystalline forms for given...

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