Article | REF: P1451 V1

Ion chromatography - Detection methods

Authors: Eric CAUDRON, Dominique PRADEAU

Publication date: March 10, 2010

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4. Spectroscopic detection methods

4.1 Refractometry

The thermostated differential refractometer is a universal, low-sensitivity detector whose principle is based on measuring the refractive index of the chromatographic eluent, relative to a reference cell.

Simple inorganic ions have extremely low refractive indices. They can therefore only be determined indirectly using an eluent modified with organic developer ions with high refractive indices, such as the anilinium cation or the phthalate anion. The main drawback of this...

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Spectroscopic detection methods