Article | REF: M2314 V1

Tin metallurgy and recycling

Author: Jacques DE CUYPER

Publication date: March 10, 1999

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3. Metallurgical treatments

3.1 Pretreatments

In order to be processed by the traditional reductive smelting process, intermediate-grade concentrates (30 to 50% Sn) containing sulfur and arsenic (e.g. in contents of a few percent and a few tenths of a percent respectively) must first undergo an oxidizing roasting operation to remove these elements by volatilization in the form of SO 2 and As 2 O 3 . Failing this pre-treatment, there is a risk, during smelting, of losing tin by volatilization in the form of sulfide and of dissolving arsenic in tin.

This is the classic process used to treat gold-bearing arsenopyrites. Above all, arsenic oxidation must not...

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