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7. Obtaining lithium metal
Lithium metal is obtained from LiCl obtained from Li 2 CO 3 .
Lithium carbonate is first purified to remove impurities interfering with electrolysis and the purity of the final lithium, in particular sodium, calcium, magnesium and sulfate ions. The most widely used process is the CO 2 process. It involves solubilizing lithium in bicarbonate form by adding CO 2 operating on a suspension of lithium carbonate in water. After filtration to remove precipitated impurities, lithium is precipitated from the filtrate in the form of carbonate by thermal decomposition at 90°C of the bicarbonate. The purified carbonate is converted to chloride by reaction with hydrochloric acid. Due to the strong...
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Obtaining lithium metal
Lithium recycling
Statistical and economic data
1. Main lithium-producing companies
The main companies producing lithium from brines are the following [60] [61] :
Sociedad Quimica y Minera (S.Q.M.) and Chemetall GmbH, Atacama salt flats, Chile;
Sociedad Chilena del Litio, Atacama salt flat (Chile);
Chemical Foote Corp, Lithium, Silver...
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Australian Mining and Metallurgy
Canadian Institute of Mining and Metallurgy
Chemical Engineering
CIM Bulletin
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Engineering and Mining Journal
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Journal of American Chemical Society
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