1. Main types of pulsed electrical regimes used
When electroplating a metal with direct current, the operator can only control one electrical parameter: current density or cathode potential, which are univocally linked in steady state.
Electrically modulated electroplating provides additional parameters: signal shape, frequency, amplitude... which, in principle, make the process more versatile. However, empirical optimization of a complex signal can only lead to a result that cannot be transposed from one metal deposit to another, and leaves the operator at a loss when faced with an unusual malfunction.
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For this reason, the modulated electrical regimes recommended in the literature are generally simple in form. The most common are shown in figure 1 :
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Main types of pulsed electrical regimes used
Bibliography
General works
- Theory and practice of pulse plating (Théorie et pratique de l'électrolyse pulsée) - Ed. PUIPPE (J.C.) and LEAMAN (F.) 247 p. 1986 American Electroplaters and Surface Finishers Society.
References
Laboratoires
French laboratories with experience in this field
Center d'Études de Chimie Métallurgique, CNRS, Vitry/Seine CETIM, Senlis.
Laboratoire de Chimie de Matériaux Inorganiques, Toulouse.
Corrosion and Surface Treatments Laboratory, Besançon.
Electrochemistry Laboratory, CNAM, Paris.
Electrochemistry Laboratory, Université...
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