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Article | REF: K585 V1

Thermodynamic properties of water

Author: Pierre PERROT

Publication date: November 10, 2006, Review date: March 18, 2024

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4. Solid-vapor equilibrium

Table 2 shows the properties of steam in equilibrium with the solid (ice I) at temperatures below 0°C. The vapor pressure of ice between 0 and – 80°C can be described, with an uncertainty of less than 0.5%, by an empirical relationship proposed by , in which pressure p is in pascals and T in kelvins :

ln (p /p t ) = a [1 – (T /T t ) –1.5 ] + b [1 – (T /T t )...

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Solid-vapor equilibrium
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