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3. Polymorphism and solid phase transitions in solution
3.1 Solubility curves
As a first step, let's consider a system with two polymorphic varieties I and II, polymorph II being more stable than polymorph I. The more stable has the lower free enthalpy:
( 4 )At equilibrium, polymorph i (i = I or II) is in contact with its saturated solution....
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Polymorphism and solid phase transitions in solution
Polymorphism and solid phase transitions in solution
Basic laboratory data for solid-phase development
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