Article | REF: J6640 V1

Trichloroethylene

Author: Philippe LEDUC

Publication date: September 10, 2003 | Lire en français

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    1. Main access routes

    The main industrial routes to trichloroethylene from ethylene and acetylene are summarized in figure 1 .

    In the main industrial processes used, trichloroethylene is co-produced with perchloroethylene.

    1.1 TRI/PER process from PPG (Pittsburgh Plate Glass Co.)

    • Process principle

      Trichloroethylene and perchloroethylene are co-produced in an oxychlorination reactor from 1,2-dichloroethane and chlorine over a fluid-bed catalyst based on potassium chloride and cupric chloride: 2C2H4Cl2+3/2Cl2+7/4O2C2HCl3+C2Cl4+7/2H2O

      ...
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