3. Chemisorption and catalytic activity
3.1 Adsorption strength and catalytic activity. Sabatier principle
The chemisorption of molecules, and in particular their dissociative chemisorption, reduces the height of the reaction activation barrier and is therefore a key step in heterogeneous catalysis. Correlations between catalytic activity and adsorption properties (notably strength) are therefore expected.
Sabatier's principle helps to rationalize the maximum sometimes obtained in diagrams representing catalytic activity as a function of a variable representative of the stability of adsorbed intermediates (volcano curve). This variable...
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Unit operations. Chemical reaction engineering
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Chemisorption and catalytic activity
Bibliography
Standards and norms
- Standard Test Method for Testing Fluid Catalytic Cracking (FCC) Catalysts by Microactivity Test. - ASTM D3907-03 -
Periodicals
ACS Catalysis, American Chemical Society.
Advanced Synthesis and Catalysis, Wiley-VCH.
Applied Catalysis–A: General; B: Environmental, Elsevier.
Catalysis Communications, Elsevier.
Catalysis Letters, Springer.
Catalysis Science and Technology, Royal Society of Chemistry.
Catalysis...
Directories
Manufacturers – Suppliers – Distributors (non-exhaustive list)
Catalyst users
BP
Eni
IFP Énergie Nouvelles
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