Article | REF: J5670 V1

Fluorinations

Author: André LANTZ

Publication date: March 10, 1998

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3. Substitution of a hydrogen atom

3.1 Elemental fluorine fluorination

As previously mentioned, fluorination of a hydrogenated compound with elemental fluorine is a very violent reaction, difficult to control and not very selective. Numerous methods and techniques designed to improve reaction control have been proposed [4] :

  • dilution of fluorine with an inert gas (nitrogen, etc.);

  • dilution of the organic product to be fluorinated with an inert solvent;

  • low-temperature fluorination ;

  • continuous processes with concentration and temperature gradients.

These fluorinations have...

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Substitution of a hydrogen atom