Article | REF: J5670 V1

Fluorinations

Author: André LANTZ

Publication date: March 10, 1998

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5. Addition of HF or fluorine to double or triple bonds

The addition of HF to olefinic hydrocarbons (or alkenes) is generally very straightforward and already takes place at low temperatures and in the absence of a catalyst [5] . The addition follows Markovnikov's rule and therefore, with the exception of ethylene, does not lead to products with groups.

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Addition of HF or fluorine to double or triple bonds