Article | REF: AM3154 V1

Kinetic modeling of an oxidation mechanism

Authors: Ludmila AUDOUIN, Xavier COLIN, Bruno FAYOLLE, Jacques VERDU

Publication date: October 10, 2005, Review date: September 1, 2016

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1. Oxidation of hydrocarbon polymers

It has been known since 1946 that the oxidation of hydrocarbon polymers P results from a radical chain process whose propagation is a two-stage mechanism.

Consensus is less firmly established with regard to priming, but three main mechanisms can be identified (equations (1) ):

ladécompositionunimoléulaire(u)des

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Oxidation of hydrocarbon polymers