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Article | REF: AM3154 V1

Kinetic modeling of an oxidation mechanism

Authors: Ludmila AUDOUIN, Xavier COLIN, Bruno FAYOLLE, Jacques VERDU

Publication date: October 10, 2005, Review date: September 1, 2016

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6. How to use the above results

Suppose we're studying a process of some kind, such as oxidative ageing-induced cross-linking. We determine its maximum speed r at different oxygen pressures p. We then have the curve r = f (p ) in a certain range of p.

Recall that C and p are related by Henry's law:

C = Sp

with :

S
 : 
depending only on temperature.

Let us now consider all possible hypotheses for the cross-linking mechanism, for example: PO2°+PO2

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