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Research and innovation | REF: RE111 V2

Reversible hydrogen storage in alanates

Authors: Junxian ZHANG, Fermin CUEVAS, Annick PERCHERON-GUÉGAN

Publication date: November 10, 2013, Review date: June 23, 2022

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4. Crystallographic structures

The crystal structures of representative alkali and alkaline-earth alanates are listed in Table 1 . Although tetra-alanates crystallize in different structures, they share many common properties. As an example, the crystallographic structure of sodium alanate is shown in figure 1 .

Tetra-alanates (M n+ (AlH 4 ) n ) consist of almost perfect tetrahedra of the [AlH 4 ] complex – interconnected by M + ...

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