Article | REF: P2720 V3

ICP-MS: inductively coupled plasma - Mass spectrometry

Authors: Hugues PAUCOT, Martine POTIN-GAUTIER

Publication date: June 10, 2010, Review date: September 1, 2018

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ABSTRACT

At this time, there is no doubt concerning the interest of the inductively coupled plasma-mass spectrometry (ICP-MS). Indeed, this type of equipment, due to, amongst others, its ease of implementation, limited number of chemical and spectral interferences and the qualities of its source, has become widely used in the laboratory, even though it does not offer very low detection limits to date. Apparatus notably include the quadrupole filter, magnetic and electrostatic sectors, the time-of-flight spectrometer, etc. Their operating principles and analytical performance are detailed in this article.

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AUTHORS

  • Hugues PAUCOT: Doctor of Science - UT2A – Ultra Traces Analyses Aquitaine, Pau

  • Martine POTIN-GAUTIER: Professor – Université de Pau et des Pays de l'Adour - CNRS, LCABIE, IPREM UMR 5254, Pau

 INTRODUCTION

Introduced commercially in 1983, ICP-MS (Inductively Coupled Plasma-Mass Spectrometry), an elemental quantification technique based on the mass spectrometric analysis of ions generated by an inductively coupled plasma, is now an integral part of many laboratories' analytical equipment. In addition to providing detection limits of the order of ng/L in dissolved phase and μg/kg in solid phase, this analytical technique is also the only one in atomic spectrometry capable of providing isotopic information.

While the ionization of elements is always based on the introduction of the sample into a noble gas plasma, i.e. an ionized but overall electrically neutral gas characterized by the presence of free electrons, various types of mass spectrometer can be used. These currently include the quadrupole filter, magnetic and electrostatic sectors, time-of-flight and, much more rarely, the ion trap.

The various operating principles, analytical performance and market status are described in this article.

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ICP-MS: inductively coupled plasma – mass spectrometry