Article | REF: K1230 V1

Reactions of organic synthesis in ionic liquids

Authors: Max Malacria, Jean-Philippe Goddard, Cyril Ollivier, Jean-Christophe PLAQUEVENT, Yves GÉNISSON, Frédéric GUILLEN

Publication date: November 10, 2008

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2. Properties of ionic liquids and initial applications

2.1 Structure and physico-chemical properties of ionic liquids

Ionic liquids have exciting physico-chemical properties. In essence, ionic liquids are salts, i.e. polar compounds. They dissolve numerous organic and inorganic compounds, and readily stabilize charged or polar solutes. Their physico-chemical properties depend on the nature and size of the two ions. Ionic liquids with chloride, bromide or trifluoroacetate anions are miscible with water (hydrophilic), whereas when the anion is a hexafluorophosphate or a bis-(trifluoromethanesulfonyl)-imide

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Properties of ionic liquids and initial applications