Article | REF: AM3325 V1

Poly(vinyl chloride) or PVC

Authors: Zdenek HRUSKA, Patrice GUESNET, Christian SALIN, Jean-Jacques COUCHOUD

Publication date: July 10, 2007

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1. Preparation

Poly(vinyl chloride) (PVC) is obtained by polymerizing vinyl chloride monomer (VCM) or monochloroethylene [1] and [3] .

The synthesis is carried out by a radical route using suitable initiators.

The discovery of this polymerization reaction by French chemist Régnault dates back to 1835.

1.1 Monomer synthesis

Since 1970, vinyl chloride monomer with the semi-developed formula :

CH 2 = CHCl

is mainly produced...

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