Article | REF: N2880 V1

Silicones or siloxanes - Structure and properties

Author: Michel BIRON

Publication date: October 10, 2007 | Lire en français

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    3. General properties

    The properties are obviously quite different for a non-reactive oil and a heat-vulcanized elastomer, but there are general features due to the silicon-rich skeleton and silicon-oxygen linkages that provide :

    • higher bond energy than other polymers;

    • improved thermo-oxidative stability;

    • greater flexibility and mobility of the polymer chain;

    • surface properties and a particular, modulable hydrophobic/organophobic character;

    • a high level of safety.

      These common properties can be grouped according to 3 origins.

    • Induced by the strength of the Si-O bond

      The binding energy of the Si-O group is 439 kJ/mol,...

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