Article | REF: AM3281 V1

Study and analysis of the surfaces of the solid polymers Physicochemical properties

Authors: Évelyne DARQUE-CERETTI, Éric FELDER, Bernard MONASSE

Publication date: January 10, 2016

You do not have access to this resource.
Click here to request your free trial access!

Already subscribed? Log in!


Français

2. Dynamic surface appearance

2.1 Characteristic temperatures and behavior

For an amorphous polymer, the main characteristic temperature is the glass transition temperatureT g , which is due to the freezing of the movement of an entire molecule (diffusion of the molecule of an amorphous polymer) or the mobility of the entire molecular segment between crystalline lamellae. At lower temperatures, shorter segment movements allow either a return to thermodynamic equilibrium or "physical aging".

The main transition in semi-crystalline polymers is crystal melting. The melting temperature depends on the thickness ℓ of the crystals and therefore on the crystallization conditions. The (absolute) melting temperatureT m ...

You do not have access to this resource.

Exclusive to subscribers. 97% yet to be discovered!

You do not have access to this resource.
Click here to request your free trial access!

Already subscribed? Log in!


The Ultimate Scientific and Technical Reference

A Comprehensive Knowledge Base, with over 1,200 authors and 100 scientific advisors
+ More than 10,000 articles and 1,000 how-to sheets, over 800 new or updated articles every year
From design to prototyping, right through to industrialization, the reference for securing the development of your industrial projects

This article is included in

Friction, wear and lubrication

This offer includes:

Knowledge Base

Updated and enriched with articles validated by our scientific committees

Services

A set of exclusive tools to complement the resources

Practical Path

Operational and didactic, to guarantee the acquisition of transversal skills

Doc & Quiz

Interactive articles with quizzes, for constructive reading

Subscribe now!

Ongoing reading
Dynamic surface appearance