Article | REF: M1720 V1

Anticorrosion coatings obtained by electrochemical polymerization

Author: François-Xavier PERRIN

Publication date: March 10, 2007, Review date: September 1, 2016

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3. Films formed by electro-oxidation of phenol derivatives

3.1 Polymerization mechanism

The acidic, neutral or alkaline nature of the electrolytic medium is the main parameter conditioning the nature of the species formed: in alkaline solution, when the CO coupling is not hindered by bulky ortho and/or para phenol groups (2,4 or 2,6-ditertbutyl or isopropylphenol, for example), the pathway leading to the formation of a stable aromatic polyether-type polymer is predominant. In contrast, an acidic or neutral environment favors the formation of phenoquinone-type species (figure

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Films formed by electro-oxidation of phenol derivatives