Article | REF: M7760 V2

Refining of stainless steels

Author: Pierre-Jean CUNAT

Publication date: March 10, 2008

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ABSTRACT

Over the last few decades, the refining techniques of stainless steels have considerably evolved, not only technically with improved mastery of the chemical composition and the control of inclusions but also economically. Gas economizing is currently the aspect which is undergoing the largest number of adaptations. After having presented the theoretical basis of decarburization, desulphurization and deoxidation, this article details the current low pressure and vacuum refining techniques whist providing their descriptions, principles, advantages and limitations.

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 INTRODUCTION

Over the past half-century, stainless steel refining techniques have evolved considerably, both technically (control of chemical composition, control of inclusionary state, etc.) and economically. A major technological leap had already been made in the 1930s with the Perrin decarburization and desulfurization process. The second technological leap forward came with reduced-pressure refining processes in the early 1970s (the AOD process and its derivatives). These gave us excellent control over decarburization and desulphurization, while considerably reducing the cost of the refining operation. With the VOD process and its derivatives (early 1980s), lowering the partial pressure of CO by means of vacuum, obtaining very low carbon, sulfur and nitrogen contents paved the way for ferritic grades with high chromium content (Cr ≈ 30%) and austenoferritic grades.

Since these major developments, we have mainly seen variants geared towards economic aspects, in particular savings in gas and raw materials (chromium and molybdenum). Finally, the refining capacity of a steel mill, which was around 500,000 tonnes per year in 1990, has been doubled in ten years, corresponding in fact to the doubling – over the same period – of stainless steel consumption worldwide.

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Stainless steel refining