Article | REF: M1530 V1

Hot-dip galvanizing - Principle

Author: Danièle QUANTIN

Publication date: September 10, 2004

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2. Galvanizing reaction

Galvanized coating is not simply a deposit of zinc on the steel surface, as paint might be. It's really a metallurgical reaction of double diffusion between zinc and iron.

This diffusion leads to the formation of layers of Fe-Zn intermetallic alloys.

The galvanized coating therefore consists of :

  • one or more layers of intermetallic compounds depending on the nature of the bath (presence of aluminium in particular) and the technological process;

  • a final layer of external zinc, which is drawn into the part by capillary action.

2.1 Formation of interfacial alloys

When a steel component is immersed in a bath of molten zinc,...

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Galvanizing reaction