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5. Reaction path for the thermal decomposition of alanates
The decomposition of alanates gives rise to intermediate phases with a lower hydrogen content, due to the desorption of this gas. The stoichiometry of the intermediate phases and the amount of hydrogen released are different for each alanate family.
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Alkaline tetra-alanates decompose and release hydrogen in three stages:
R1 :
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Reaction path for the thermal decomposition of alanates
Thermodynamic properties and reversibility of absorption/desorption
Bibliography
Websites
COST Action MP1103 on "Nanostructured materials for Solid State Hydrogen Storage". http://www.cost-mp1103.eu/WebPages/costmp1103.php
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Rare Earth Metallurgical Chemistry Team /ICMPE/CNRS https://www.icmpe.cnrs.fr/
Groupement de Recherche CNRS " Acthyf " (Actors of the hydrogen community in France) http://www.gdr-acthyf.cnrs.fr/
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