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4. Catalytic Staudinger reaction
4.1 Introduction to the Staudinger reaction
Another major reaction promoted by phosphines is the Staudinger transformation . However, Staudinger reduction must be distinguished from Staudinger ligation (figure 14 ). Both reactions begin with the formation of an iminophosphorane intermediate, starting from an azide (R-N 3 ). This species possessing a P=N double bond was discovered in 1919 by Staudinger and Meyer...
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Unit operations. Chemical reaction engineering
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Catalytic Staudinger reaction
Catalytic Mitsunobu reaction
Bibliography
Standards and norms
- Environmental management – Lifecycle analysis – Requirements and guidelines - NF EN ISO 14044 - (2006)
- Lifecycle analysis – Principles and framework - NF EN ISO 14040 - (2006)
Patents
O'BRIEN (C.J.) (University of Texas, USA), Catalytic Wittig and Mitsunobu reactions. US Patent 8901365, (2014).
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