Article | REF: IN405 V1

Phosphine redox catalysis

Authors: Charlotte LORTON, Arnaud VOITURiEZ

Publication date: March 10, 2021

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6. Catalytic Appel reaction

6.1 Introduction to Call Reaction

Another nucleophilic substitution reaction promoted by phosphines is the Appel reaction . In this transformation, alcohols (R 3 C-OH) are converted to alkyl halides (R 3 C-X), using a stoichiometric amount of triphenylphosphine. This reaction is commonly used in academic research and in industry since it allows the rapid creation of C-X bonds that are very useful for obtaining more molecular diversity....

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Catalytic Appel reaction