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3. Second-generation molecular shuttles
3.1 Wider, faster
The study of other copper-based molecular machines has revealed that one of the critical factors influencing the speed of their movements is steric hindrance around the complexation sites . Thus, when a polypyridine ligand is functionalized on the positions adjacent to the nitrogen atoms, this considerably reduces the decomplexation speed, or "unhooking", of the unstable complexes and thus delays the machine's setting in motion.
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Unit operations. Chemical reaction engineering
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Second-generation molecular shuttles
Conclusion
Bibliography
Websites
Biography of Jean-Pierre Sauvage http://www.academie-sciences.fr/membres/S/Sauvage_JP_bio.htm
Jean-Pierre Sauvage's lecture http://www.canal-u.tv/producteurs/université_de_tous_les_savoirs...
Directory
Laboratoires
LSAMM - Laboratory for the Synthesis of Multifunctional Molecular Assemblies University of Strasbourg http://lsamm.fr/
IBMM - Institut des Biomolécules Max Mousseron École Nationale Supérieure de Chimie de Montpellier http://www.glycorotaxane.fr/index.html
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