Article | REF: J1607 V1

Electrochemistry. Current-potential characteristics: theory (part 2)

Authors: Bernard TRÉMILLON, Gérard DURAND

Publication date: June 10, 2001

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1. Reduction of metal cations

In the case of an electrode consisting of the metal M (solid) conjugated to the metal ion M z+ reducible to M, a metal itself oxidizable to M z+ (M z+ + z e - = M¯), and if we're dealing with a fast system, we can apply the relationship (assuming that the chemical potential of M¯ is constant):

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Reduction of metal cations