Overview
ABSTRACT
The use of fuels from biomass is one of the paths to the transition toward the non-fossil energies. In bio-refineries, different processes (biological, thermochemical, etc.) transform feedstocks of very different compositions (vegetable oils, wood, straw, residues, etc.) to obtain alcohols, esters and synthetic fuels. The behavior of metallic materials with respect to the corrosion of the equipment of these new processes is an important parameter to ensure the reliability of this industry. In addition, the presence of oxygenated compounds in these new fuels can lead to corrosion and fouling in storage equipment and in the internal combustion chambers of heat engines and turbojets. This article from aims to make a state of the art of these phenomena and their prevention methods.
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François ROPITAL: Doctorate from the École nationale supérieure des mines de Saint-Étienne (France) - HDR from Pierre et Marie Curie University - Associate Professor – Expert IFP Énergies nouvelles - Engineer from the Lyon National Institute of Applied Sciences (INSA) - Univ. Lyon, INSA Lyon, MATEIS UMR CNRS 5510, Villeurbanne, France - IFP Énergies Nouvelles, Solaize, France
INTRODUCTION
In order to ensure the transition to non-fossil fuels, the use of biofuels is one way of reducing CO 2 emissions. The biofuels industry comprises a whole range of processes making it possible to obtain, from a variety of incoming sources (energy crops, lignocellulosic biomass, vegetable oils and animal fats, etc.), chemical compounds that can replace or be added to petroleum-based fuels. These new feedstocks have led to the adaptation of oil refining processes and the development of new biorefinery processes.
To ensure the reliability of equipment used in these new technologies, it is essential to select materials that can withstand these new, potentially corrosive environments. The aim of this article is to provide information on the various corrosion phenomena encountered in biorefineries, and how to protect against them by making appropriate choices of materials and/or anti-corrosion treatments.
As new contaminants may be present in biofuels (gasoline, kerosene, diesel) during transport, storage and combustion, corrosion damage and/or fouling of pipes, tanks, engines and turbojets may occur. This article also looks at how to make the right choice of materials and/or anti-corrosion and anti-deposition treatments.
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KEYWORDS
synthetic fuels | biorefineries | oxygenated compounds
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Corrosion of metallic materials during biofuel production and use
Bibliography
Standards and norms
- Damage mechanisms affected fixed equipment in the refinery industry - API 571 - 2020
- Base resource document on risk-based inspection - API 581 - 2016
- Stress Corrosion Cracking of Carbon Steel in Fuel-Grade Ethanol: Review, Experience Survey, Field Monitoring, and Laboratory Testing - API 939D - 2007
- Steels for hydrogen at elevated temperature and pressures in petroleum refineries and petrochemical...
Directory
Organizations – Federations – Associations (non-exhaustive list)
French Anticorrosion Center (CEFRACOR) https://www.cefracor.org/
European Federation of Corrosion (EFC) https://efcweb.org/
Association of Materials Prorection and Performance...
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